Demonstration

Classification and labelling Print

  

Hazard pictograms

 

 
 
 
Exploding bomb
 
Flame
 
Flame over cercle
 
Gas cylinder
       
 
 
 
Corrosion
 
Skull and crossbones
 
Health hazard
 
Exclamation mark
       
      
Environment
      

 

Signal words

A signal word means a word used to indicate the relative level of severity of hazard and alert the reader to a potential hazard on the label .

The signal words used in the GHS are:

"DANGER" et "WARNING"

 

Hazard statements H

A hazard statement means a phrase assigned to a hazard class and category that describes the nature of the hazards of a hazardous product, including, where appropriate, the degree of hazard..

 

Precautionary statements P and pictograms

A precautionary statement means a phrase (and/or pictograms)that describe recommended measuresthat should be taken to minimise or prevent adverse effects resulting from exposure to a hazardous product, or improper storage or handling of a hazardous product..

 

  

Allocation of label elements

Physico-chemical hazards
 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Explosives
Unstable explosives
Danger
H200: Unstable explosive
 
Division 1.1
Danger
H201: Explosive; mass explosion hazard
 
Division 1.2
Danger
H202: Explosive; severe projection hazard
 
Division 1.3
Danger
H203: Explosive; fire, blast or projection hazard
 
Division 1.4
Warning
H204: Fire or projection hazard
 
Division 1.5
No pictogram
1.5 on orange
background
Danger
H205: May mass explode in fire
 
Division 1.6
No pictogram
1.6 on orange
background
  

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Flammable Gases
Category 1
Danger
H220: Extremely flammable gas
 
Category 2
 
Warning
H221: Flammable gas

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Flammable aerosols
Category 1
Danger
H222: Extremely flammable aerosol
 
Category 2
Warning
H223: Flammable aerosol

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Oxidizing Gases
Category 1
Danger
H270: May cause or intensify fire; oxidizer

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Gases under pressure
Gaz
comprimé
Warning
H280: Contains gas under pressure; may explode if heated
 
Gaz
liquéfié
Warning
H280: Contains gas under pressure; may explode if heated
 
Gaz liquide réfrigéré
Warning
H281: Contains refrigerated gas; may cause cryogenic burns or injury
 
Gaz dissous
Warning
H280: Contains gas under pressure; may explode if heated

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Flammable liquids
Category 1
Danger
H224: Extremely flammable liquid and vapour
 
Category 2
Danger
H225: Highly flammable liquid and vapour
 
Category 3
Warning
H226: Flammable liquid and vapour
 
Category 4
 
Warning
H227: Combustible liquid

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Flammable solids
Category 1
Danger
H228: Flammable solid
 
Category 2
Warning
H228: Flammable solid

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Self-reactive substances and mixtures
Type A
Danger
H240: Heating may cause an explosion
 
Type B

Danger
H241: Heating may cause a fire or explosion
 
Type C et D
Danger
H242: Heating may cause a fire
 
Type E et F
Warning
H242: Heating may cause a fire
 
Type G
   

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Pyrophoric liquids
Category 1
Danger
H250: Catches fire spontaneously if exposed to air

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Pyrophoric solids
Category 1
Danger
H250: Catches fire spontaneously if exposed to air

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Self-heating substances and mixtures
Category 1
Danger
H251: Self-heating; may catch fire
 
Category 2
Warning
H252: Self-heating in large quantities; may catch fire

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Substances and mixtures, which in contact with water, emit flammable gases
Category 1
Danger
H260: In contact with water releases flammable gases which may ignite spontaneously
 
Category 2
Danger
H261: In contact with water releases flammable gas
 
Category 3
Warning
H261: In contact with water releases flammable gas

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Oxidizing liquids
Category 1
Danger
H271: May cause fire or explosion; strong oxidizer
 
Category 2
Danger
H272: May intensify fire; oxidizer
 
Category 3
Warning
H272: May intensify fire; oxidizer

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Oxidizing solids
Category 1
Danger
H271: May cause fire or explosion; strong oxidizer
 
Category 2
Danger
H272: May intensify fire; oxidizer
 
Category 3
Warning
H272: May intensify fire; oxidizer

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Organic peroxides
Type A
Danger
H240: Heating may cause an explosion
 
Type B

Danger
H241: Heating may cause a fire or explosion
 
Type C et D
Danger
H242: Heating may cause a fire
 
Type E et F
Warning
H242: Heating may cause a fire
 
Type G
   

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Corrosive to metals
Category 1
Warning
H290: May be corrosive to metals

 

Health hazards
 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Acute toxicity: oral
Category 1
Danger
H300: Fatal if swallowed
 
Category 2
Danger
H300: Fatal if swallowed
 
Category 3
Danger
H301: Toxic if swallowed
 
Category 4
Warning
H302: Harmful if swallowed
 
Category 5
 
Warning

H303: May be harmful if swallowed

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Acute toxicity: skin
Category 1
Danger
H310: Fatal in contact with skin
 
Category 2
Danger
H310: Fatal in contact with skin
 
Category 3
Danger
H311: Toxic in contact with skin
 
Category 4
Warning
H312: Harmful in contact with skin
 
Category 5
 
Warning

H313: May be harmful in contact with skin

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Acute toxicity: inhalation
Category 1
Danger
H330: Fatal if inhaled
 
Category 2
Danger
H330: Fatal if inhaled
 
Category 3
Danger
H331: Toxic if inhaled
 
Category 4
Warning
H332: Harmful if inhaled
 
Category 5
 
Warning

H333: May be harmful if inhaled

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Skin corrosion / Irritation
Category 1A
Danger
H314: Causes severe skin burns and eye damage
 
Category 1B
Danger
H314: Causes severe skin burns and eye damage
 
Category 1C
Danger
H314: Causes severe skin burns and eye damage
 
Category 2
Warning
H315: Causes skin irritation
 
Category 3
 
Warning
H316: Causes mild skin irritation

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Serious eye damage / eye irritation
Category 1
Danger
H318: Causes serious eye damage
 
Category 2A
Warning
H319: Causes serious eye irritation
 
Category 2B
 
Warning
H320: Causes eye irritation

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Respiratory sensibilization
Category 1
Danger
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Skin sensibilization
Category 1
Warning
H317: May cause an allergic skin reaction

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Germ cell mutagenicity
Category 1A
Danger
H340: May cause genetic defects (*)
 
Category 1B
Danger
H340: May cause genetic defects (*)
 
Category 2
Warning
H341: Suspected of causing genetic defects (*)

(*) state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard.

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Carcinogenicity
Category 1A
Danger
H350: May cause cancer (*)
 
Category 1B
Danger
H350: May cause cancer (*)
 
Category 2
Warning
H351: Suspected of causing cancer (*)

(*) state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard.

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Toxic to reproduction
Category 1A
Danger
H360: May damage fertility or the unborn child (*)
 
Category 1B
Danger
H360: May damage fertility or the unborn child (*)
 
Category 2
Warning
H361: Susceptible de nuire à la fertilité ou au foetus (*)
 
Category supplémentaire pou les effets sur ou via l'allaitement
  
H362: Suspected of damaging fertility or the unborn child

(*) state specific effect if known, state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard.

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Specific target organ toxicity (single exposure)
Category 1
Danger
H370: Causes damage to organs (**) (*)
 
Category 2
Warning
H371: May cause damage to organs (**) (*)
 
Category 3
Warning

(Respiratory tract irritation)
H335: May cause respiratory irritation

ou

(Narcotic effects)
H336: May cause drowsiness or dizziness

(*) state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard.
(**) state all organs affected, if known.

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Specific target organ toxicity (repeated exposure)
Category 1
Danger
H372: Causes damage to organs (**) through prolonged or repeated exposure (*)
 
Category 2
Warning
H373: May cause damage to organs (**) through prolonged or repeated exposure (*)

(*) state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard.
(**) state all organs affected, if known.

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Aspiration hazard
Category 1
Danger
H304: May be fatal if swallowed and enters airways
 
Category 2
Warning
H305: May be harmful if swallowed and enters airways

 

Environmental hazards
 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Aquatic toxicity (acute)
Category 1
Warning
H400: Very toxic to aquatic life
 
Category 2
  
H401: Toxic to aquatic life
 
Category 3
  
H402: Harmful to aquatic life

 

Hazard class

Category

Hazard pictogram
Signal word
Hazard statement
Aquatic toxicity (chronic)
Category 1
Warning
H410: Very toxic to aquatic life with long lasting effects
 
Category 2
 
H411: Toxic to aquatic life with long lasting effects
 
Category 3
  
H412: Harmful to aquatic life with long lasting effects
 
Category 4
  
H413: May cause long lasting harmful effects to aquatic life
 
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